A box of 1.00m3 is filled with nitrogen at 1.50 atm at 300K. The box has a hole of an area 0.010 mm2. How much time is required for the pressure to reduce by 0.10 atm, if the pressure outside is 1 atm.

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    Answered by

    Payal Gupta | Contributor-Level 10

    4 months ago

    This is a long answer type question as classified in NCERT Exemplar

    Given volume V = 1m3

    area = 0.01mm2

    = 8.01 × 10 - 6 m2= 10 - 8 m2

    Temperature both inside and outside are equal

    So initial pressure inside the box = 1.50atm

    Final pressure inside the box= 0.1atm

    Assuming Vx= speed of nitrogen molecule in x direction

    ni = number of molecules per unit volume in a time interval of ? T

    Let area of the wall, number of particles colliding in time

    ? t = 1 2 n i (vx ? t )A , here we use ½ because particle moves both in positive and negative direction.

    Vx2+ Vy2+ Vz2= Vrms2

    Vx2= Vrms2/3 if all three velocities are equal.

    ½ mvrms2= 3/2KBT/m

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