Deutrium was discovered in 1931by Harold Urey by measuring the small change in wavelength for a particular transition in 1H and 2 This is because, the wavelength of transition depends to a certain extent on the nuclear mass. If nuclear motion is taken into account, then the electrons and nucleus revolve around their common centre of mass. Such a system is equivalent to a single particle with a reduced mass μ , revolving around the nucleus at a distance equal to the electron-nucleus separation. Here μ = meM / ( me + M ) where M is the nuclear mass and me is the electronic mass. Estimate the percentage difference in wavelength for the 1st line of the Lyman series in . 1H and 2H . (Mass of 1H nucleus is 1.6725 × 10-27kg , mass of  1H nucleus is 3.3374 × 10-27kg 3.3374 × 10-27 ?g , Mass of electron = 9.109 × 10-31 kg ).

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    Vishal Baghel | Contributor-Level 10

    3 months ago

    This is a Long Answer Type Questions as classified in NCERT Exemplar

    Explanation- total energy of electron

    E= μ Z 2 e 4 8 ε o 2 h 2 1 n 2

    The frequency hv= μ e 4 8 ε o 2 h 2 1 - 1 4 = μ e 4 8 ε o 2 h 2 3 4

    ? λ = λ D - λ H

    100 × ? λ λ H = λ D - λ H λ H × 100 = μ D - μ H μ H × 100

    = m e M D m e + M H - m e M D m e - M H m e M D m e + M H × 100

    When me<H<

    after solving we get 2.714 × 10 - 2 %

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