Show that the first few frequencies of light that is emitted when electrons fall to nth level from levels higher than n, are approximate harmonics (i.e., in the ratio 1:2:3 …) when n >> 1.

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    Vishal Baghel | Contributor-Level 10

    3 months ago

    This is a Short Answer Type Questions as classified in NCERT Exemplar

    Explanation- The frequency of any line in a series in the spectrum of hydrogen like atoms corresponding to the transition of electrons from (n+ p) level to nth level can be expressed as a difference of two terms;

    From the formula we can say that v=cRZ2 { 1 ( n + p ) 2 - 1 n 2 }

    Where p =1,2,3, … R os rydberg constant

    When p<

    V=cRZ2 { 1 n 2 ( 1 + p n ) - 2 - 1 n 2 }

    V=cRZ2 { 1 n 2 - 2 p n 3 - 1 n 2 }

    By binomial theorem

    V=cRZ2 { 2 p n 3 = 2 c R Z 2 n 3 p

    Thus, the first few frequencies of light that is emitted when electrons fall to the nth level

    from levels higher than n, are approximate harmonic (i.e., in the ratio 1 : 2 : 3 …) when

    n >> 1 .

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