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Hi Vishal,
Sundar Pichai has done metallurgical engineering from Indian Institute of Technology Kharagpur, MS in material sciences and engineering from Stanford University, and MBA from the Wharton School, University of Pennsylvania.
If you want to become a CEO of a good IT company, then you should opt for CSE in a good college. After that, Masters in the same and work for few years in the IT field. This will help you to understand the internal working of an organisation and also familiarize with the demands in the IT industry. You should also undertake some challenging projects. This will enhance your skill and you will get a good exposure.
You need to pursue MBA from a good institute and work for some more years. Later, if you do well, you can become the CEO of a good company.
If you have good ideas, then start your own business after doing extensive market research.
Hope it helps!