Angular momentum of electron in 3rd stationary orbit of hydrogen atom is
Angular momentum of electron in 3rd stationary orbit of hydrogen atom is
Orbital angular momentum =
=
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Radius of Bohr’s orbit
Radius of Bohr’s orbit for hydrogen,
For third orbit (R3) = = r3 and
Fourth orbit (R4) =
For irreversible expansion of an ideal gas under isothermal condition
ΔU = 0, ΔS (Total) ≠ 0
105.8 × (2/4) = 52.9 pm ⇒ rLi+ + rX- = 52.9 × (3²/3) = 158.7 pm
Bohr's theory accounts for the line spectrum of single electron species but Li? has two electrons. Bohr's theory fails to explain splitting of spectral lines in presence of magnetic field i.e. Zeeman effect.
ΔR? = (a? /3) (16 – 9)
ΔR? = (a? /2) (16 – 9)
∴ ΔR? /ΔR? = 2/3
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