Given below are two statements:
Statement I: Bohr's theory accounts for the stability and line spectrum of Li²? ion.
Statement II: Bohr's theory was unable to explain the splitting of spectral lines in the presence of a magnetic field.
In the light of the above statements, choose the most appropriate answer from the options given below:
Given below are two statements:
Statement I: Bohr's theory accounts for the stability and line spectrum of Li²? ion.
Statement II: Bohr's theory was unable to explain the splitting of spectral lines in the presence of a magnetic field.
In the light of the above statements, choose the most appropriate answer from the options given below:
Option 1 -
Both statement I and statement II are true
Option 2 -
Statement I is true but statement II is false.
Option 3 -
Both statement I and statement II are false
Option 4 -
Both statement I and statement II are false
-
1 Answer
-
Correct Option - 4
Detailed Solution:Bohr's theory accounts for the line spectrum of single electron species but Li? has two electrons. Bohr's theory fails to explain splitting of spectral lines in presence of magnetic field i.e. Zeeman effect.
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=
Radius of Bohr’s orbit
Radius of Bohr’s orbit for hydrogen,
For third orbit (R3) = = r3 and
Fourth orbit (R4) =
For irreversible expansion of an ideal gas under isothermal condition
ΔU = 0, ΔS (Total) ≠ 0
105.8 × (2/4) = 52.9 pm ⇒ rLi+ + rX- = 52.9 × (3²/3) = 158.7 pm
ΔR? = (a? /3) (16 – 9)
ΔR? = (a? /2) (16 – 9)
∴ ΔR? /ΔR? = 2/3
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