3.16. Among the second period elements, the actual ionization enthalpies are in the order: Li
Explain why

(i)  Be has higher ?i H than B?

(ii) O has lower ?i H than N and F?   

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10 months ago

3.16.  (i) In the electronic configuration of Be (1s2 2s2) the outermost electron is present in 2s-orbital while in B (1s2 2s2 2p1) it is present in 2p-orbital. Since 2s – electrons are more strongly attracted by the nucleus than 2p-electrons, therefore, lesser amount of energy is required to knock

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Among isoelectronic monoatomic species, size is inversely proportional to atomic number. Hence among isoelectronic species Na? , O²? , N³? , F? (having the nearest noble gas configuration);
Order of size is Na? < F? < O²? < N³?
N³? has least atomic number hence the largest size

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Electron gain enthalpy increases with electro negativity chlorine has higher electron gain enthalpy than fluorine (exception)

In isoelectronic species nuclear charge can be approximated as
Nuclear charge ≈ z / no. of electrons
Al³? Mg²? Na? F? O²? N³?
Nuclear Charge: 13/10 12/10 11/10 9/10 8/10 7/10
Minimum nuclear charge is in N³? and maximum is in Al³?
So order should be
Al³? < Mg²? < Na? < F? < O²? < N³?

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Chemistry Ncert Solutions Class 11th 2023

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