3.24. Describe the theory associated with the radius of an atom as it:

(a) Gains an electron (b) Loses an electron?

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3.24.  (a) Gain of an electron leads to the formation of an anion. The size of an anion will be larger than that of the parent atom because the addition of one or more electrons would result in increased repulsion among electrons and decrease in effective nuclear charge.

(b) Loss of an electron from

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Among isoelectronic monoatomic species, size is inversely proportional to atomic number. Hence among isoelectronic species Na? , O²? , N³? , F? (having the nearest noble gas configuration);
Order of size is Na? < F? < O²? < N³?
N³? has least atomic number hence the largest size

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Electron gain enthalpy increases with electro negativity chlorine has higher electron gain enthalpy than fluorine (exception)

In isoelectronic species nuclear charge can be approximated as
Nuclear charge ≈ z / no. of electrons
Al³? Mg²? Na? F? O²? N³?
Nuclear Charge: 13/10 12/10 11/10 9/10 8/10 7/10
Minimum nuclear charge is in N³? and maximum is in Al³?
So order should be
Al³? < Mg²? < Na? < F? < O²? < N³?

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Chemistry Ncert Solutions Class 11th 2023

Chemistry Ncert Solutions Class 11th 2023

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