7.45. The-first ionization constant of H2S is 9.1 x 10-8. Calculate the concentration of HS– ions in its 0.1 M solution and how will this concentration be affected if the solution is 0.1 M in HCl also? If the second dissociation constant of H2S is 1.2 x 10--13, calculate the concentration of S2-under both conditions.
7.45. The-first ionization constant of H2S is 9.1 x 10-8. Calculate the concentration of HS– ions in its 0.1 M solution and how will this concentration be affected if the solution is 0.1 M in HCl also? If the second dissociation constant of H2S is 1.2 x 10--13, calculate the concentration of S2-under both conditions.
(i) To calculate [HS−] in absence of HCl:
Let, [HS−] = x M.
H2? S? H+ + HS−
The initial concentrations of H2? S, H+ and HS− are 0.1 M, 0 M and 0 M respectively.
Their final concentrations are 0.1-x M, x M and x M respectively.
Ka? = [H2? S] [H+] [HS−]?
9.1*10−8 = x * x / (0.1−x)?
In the denominat
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Chemistry Ncert Solutions Class 11th 2023
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