8.25 Describe the oxidising action of potassium dichromate and write the ionic equations for its reaction with: (i) iodide (ii) iron(II) solution and (iii) H2S
8.25 Describe the oxidising action of potassium dichromate and write the ionic equations for its reaction with: (i) iodide (ii) iron(II) solution and (iii) H2S
8.25 K2Cr2O7 acts as a very strong oxidizing agent in acidic medium. K2Cr2O7 gets reduced and acts as an oxidizing agent by oxidizing Iodide to iodine
(i) K2Cr2O7 oxidizes iodide to iodine
Cr2O72-+ 14H++ 6e-→ 2Cr3+ + 7H2O
2I-→ I2 + 2e- } x3
Overall: Cr2O72-+ 14H++ 6I-→ 2Cr3+ + 7H2O+ 3I2
(ii) K2Cr2O7 oxid
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K2Cr2O7 + H2O2 + H2SO4->
Potassium permanganate in alkaline medium oxidise lodide to lodate.
Compound A is
KMnO4 decomposes upon heating at 513 K and forms K2MnO4 and MnO2.
2KMnO4
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Chemistry Ncert Solutions Class 12th 2023
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