Calculate the wavelength for the emission transition if it starts from the orbit having radius 1.3225 nm and ends at 211.6 pm. Name the series to which this transition belongs and the region of the spectrum.
Calculate the wavelength for the emission transition if it starts from the orbit having radius 1.3225 nm and ends at 211.6 pm. Name the series to which this transition belongs and the region of the spectrum.
Radius of orbit of H like species = (0.529 / Z) n2Å = (52.9 / Z) n2 pm
r1 = 1.3225 nm = 1322.5 pm = (52.9 / Z) n12
r2 = 211.6 pm = 211.6 pm = (52.9 / Z) n22
∴ r1 / r2 = 1322.5 / 211.6
=>n12 /n22 = 6.25
=> n1/n2= (6.25)1/2 = 2.5
=> n1 = 2.5 n2
=> 10 n1= 25 n2
=> 2 n1= 5 n2
If n1 = 2, then n2 = 5. That means
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In 4d orbital, n = 4 and
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Radial nodes = 4 – 2 – 1 = 1
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Here, number of unpaired electrons, n = 1
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= 173 × 10-2 B.M
=
= (At constant pressure)
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Chemistry Ncert Solutions Class 11th 2023
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