Electronic configurations of four elements A, B, C and D are given below:
(A) 1s2 2s2 2p6 (B) 1s2 2s2 2p4
(C) 1s2 2s2 2p6 3s1 (D) 1s2 2s2 2p5
Which of the following is the correct order of increasing tendency to gain electron :
(i) A < C < B < D
(ii) A < B < C < D
(iii) D < B < C < A
(iv) D < A < B < C
Electronic configurations of four elements A, B, C and D are given below:
(A) 1s2 2s2 2p6 (B) 1s2 2s2 2p4
(C) 1s2 2s2 2p6 3s1 (D) 1s2 2s2 2p5
Which of the following is the correct order of increasing tendency to gain electron :
(i) A < C < B < D
(ii) A < B < C < D
(iii) D < B < C < A
(iv) D < A < B < C
This is a Multiple Choice Questions as classified in NCERT Exemplar
Option (i)
The electron gain enthalpy of 2p orbital is higher than that of the 3s orbital
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Among isoelectronic monoatomic species, size is inversely proportional to atomic number. Hence among isoelectronic species Na? , O²? , N³? , F? (having the nearest noble gas configuration);
Order of size is Na? < F? < O²? < N³?
N³? has least atomic number hence the largest size
Electron gain enthalpy increases with electro negativity chlorine has higher electron gain enthalpy than fluorine (exception)
In isoelectronic species nuclear charge can be approximated as
Nuclear charge ≈ z / no. of electrons
Al³? Mg²? Na? F? O²? N³?
Nuclear Charge: 13/10 12/10 11/10 9/10 8/10 7/10
Minimum nuclear charge is in N³? and maximum is in Al³?
So order should be
Al³? < Mg²? < Na? < F? < O²? < N³?
(a) The element V has the highest first ionization enthalpy (? iH1) and positive electron gain enthalpy (? egH) and hence it is the least reactive element. Since inert gases have positive? egH, therefore, the element-V must be an inert gas. The values of? iH1, ? iH2 and? egH match
This is a Matching Type Questions as classified in NCERT Exemplar
i
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Chemistry NCERT Exemplar Solutions Class 11th Chapter Three 2025
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