Emission transitions in the Paschen series end at orbit n = 3 and start from orbit n and can be represented as v = 3.29 x 1015 (Hz) [1/32 – 1 /n2]. Calculate the value of n if the transition is observed at 1285 nm. Find the region of the spectrum.
Emission transitions in the Paschen series end at orbit n = 3 and start from orbit n and can be represented as v = 3.29 x 1015 (Hz) [1/32 – 1 /n2]. Calculate the value of n if the transition is observed at 1285 nm. Find the region of the spectrum.
Given, ν = (3.29 x 1015 Hz) (1/32 – 1/n2)
= (3.29 x 1015 Hz) (1/32 – 1/n2)
(3 x 108 ms-1) / (1.285 x 10-6 m) = (3.29 x 1015 Hz) (1/32 – 1/n2)
2.3346 x 1014 = (3.29 x 1015 Hz) (1/32 – 1/n2)
2.3346 / 32.9 = 1/32 – 1/n2
0.071 = 1/9 – 1/n2
1/n2 = 1/9 – 0.071= 0.111 – 0.071 = 0.04
n2 = 1/ 0.04 = 25
=> n = 5
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In 4d orbital, n = 4 and
Radial nodes =
Radial nodes = 4 – 2 – 1 = 1
And angular nodes,
Here, number of unpaired electrons, n = 1
Spin only moment ;
= 173 × 10-2 B.M
=
= (At constant pressure)
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Chemistry Ncert Solutions Class 11th 2023
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