Illustrate by taking examples of transition elements and non-transition elements that oxidation states of elements are largely based on electronic configuration.

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The electronic configuration of Cr= 1s2 2s2 2p6 3s2 3p6 4s1 3d10

The electronic configuration of Cr after losing one electron= 1s2 2s2 2p6 3s2 3p6 3d10

The electronic configuration of F= 1s2 2s2 2p6 3s2 3p5

The electronic configuratio

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Among isoelectronic monoatomic species, size is inversely proportional to atomic number. Hence among isoelectronic species Na? , O²? , N³? , F? (having the nearest noble gas configuration);
Order of size is Na? < F? < O²? < N³?
N³? has least atomic number hence the largest size

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Electron gain enthalpy increases with electro negativity chlorine has higher electron gain enthalpy than fluorine (exception)

In isoelectronic species nuclear charge can be approximated as
Nuclear charge ≈ z / no. of electrons
Al³? Mg²? Na? F? O²? N³?
Nuclear Charge: 13/10 12/10 11/10 9/10 8/10 7/10
Minimum nuclear charge is in N³? and maximum is in Al³?
So order should be
Al³? < Mg²? < Na? < F? < O²? < N³?

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Chemistry NCERT Exemplar Solutions Class 11th Chapter Three 2025

Chemistry NCERT Exemplar Solutions Class 11th Chapter Three 2025

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