In which of the following options order of arrangement does not agree with the variation of property indicated against it?

(i) Al3+ < Mg2+ < Na+ < F (increasing ionic size)

(ii) B < C < N < O (increasing first ionisation enthalpy)

(iii) I < Br < Cl < F (increasing electron gain enthalpy)

(iv) Li < Na < K < Rb (increasing metallic radius)

13 Views|Posted 8 months ago
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1 Answer
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8 months ago

This is a Multiple Choice Questions as classified in NCERT Exemplar

Option (ii)& (iii)

The ionization enthalpy of N is higher than that of F because it possess half filled orbital which provide it extra stability due to symmetry.

 As the atomic size of F is much smaller thus its electron gain enthalpy

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Among isoelectronic monoatomic species, size is inversely proportional to atomic number. Hence among isoelectronic species Na? , O²? , N³? , F? (having the nearest noble gas configuration);
Order of size is Na? < F? < O²? < N³?
N³? has least atomic number hence the largest size

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Electron gain enthalpy increases with electro negativity chlorine has higher electron gain enthalpy than fluorine (exception)

In isoelectronic species nuclear charge can be approximated as
Nuclear charge ≈ z / no. of electrons
Al³? Mg²? Na? F? O²? N³?
Nuclear Charge: 13/10 12/10 11/10 9/10 8/10 7/10
Minimum nuclear charge is in N³? and maximum is in Al³?
So order should be
Al³? < Mg²? < Na? < F? < O²? < N³?

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Chemistry NCERT Exemplar Solutions Class 11th Chapter Three 2025

Chemistry NCERT Exemplar Solutions Class 11th Chapter Three 2025

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