On heating with concentrated NaOH solution in an inert atmosphere of CO2, white phosphorus gives a gas. Which of the following statements is incorrect about the gas? 

(i) It is highly poisonous and smells like rotten fish. 

(ii) It's solution in water decomposes in the presence of light. 

(iii) It is more basic than NH3.

(iv) It is less basic than NH3.

2 Views|Posted 9 months ago
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9 months ago

This is a multiple choice answer as classified in NCERT Exemplar

Correct option is (iii)

When heated with concentrated NaOH in an inert CO2 environment. It formsPH3

P4 + 3NaOH + 3H2O→PH3 + 3NaH2PO2

As we progress from the top to the bottom in a group, the basic character of hydrides reduces PHis basic

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Chemistry NCERT Exemplar Solutions Class 12th Chapter Seven 2025

Chemistry NCERT Exemplar Solutions Class 12th Chapter Seven 2025

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