The electronic configuration of valence shell of Cu is 3d104s1 and not 3d94s2 . How is this configuration explained?

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9 months ago

This is a Short Answer Type Questions as classified in NCERT Exemplar

Ans: As per the Hund's rule the half filled and fully filled orbital leads to the extra stability due to the symmetry thus fully filled 3d and half filled 4s is preferred.

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In 4d orbital, n = 4 and l=2

Radial nodes = nl1

Radial nodes = 4 – 2 – 1 = 1

And angular nodes,  l=2

B 2 + σ 1 s 2 s * 1 s 2 σ 2 s 2 σ * 2 s 2 π 2 p 1  

Here, number of unpaired electrons, n = 1

Spin only moment ;    μ = n ( n + 2 ) B . M

= 173 × 10-2 B.M

 

...Read more

Δ H = Δ U + Δ ( P V )

= Δ U + P Δ V + V Δ P

= Δ U + P Δ V   (At constant pressure)

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Chemistry NCERT Exemplar Solutions Class 11th Chapter Two 2025

Chemistry NCERT Exemplar Solutions Class 11th Chapter Two 2025

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