The reaction of white phosphorous on boiling with alkali in inert atmosphere resulted in the formation of product 'A'. The reaction of 1 mol of 'A' with excess of AgNO₃ in aqueous medium gives _______ mol(s) of Ag. (Round off to the nearest integer).
The reaction of white phosphorous on boiling with alkali in inert atmosphere resulted in the formation of product 'A'. The reaction of 1 mol of 'A' with excess of AgNO₃ in aqueous medium gives _______ mol(s) of Ag. (Round off to the nearest integer).
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1 Answer
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P? + 3NaOH + 3H? O → PH? + 3NaH? PO? (A)
Here, NaH? PO? is a reducing agent.
NaH? PO? + AgNO? + H? O → Ag + HNO? + NaH? PO?
Equivalents of NaH? PO? = equivalents of Ag (n-factor of NaH? PO? = 4)
1 mole × 4 = n moles of Ag × 1
So, moles of Ag = 4.
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