When 5.1g of solid NH4HS is introduced into a two litre evacuated flask at 27°C, 20% of the solid decomposes into gaseous ammonia and hydrogen sulphide. The Kp for the reaction at 27°C is x * 10-2. The value of x is_______. (Integer answer)

[Given R = 0.082 L atm K-1 mol-1]

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7 months ago

Moles of NH4HS initially taken = 5 . 1 5 1 = 0 . 1 m o l  

N H 4 H S ( S ) + N H 3 ( g ) + H 2 S ( g )                             

t =  0       0.1 mol               0            0

t =    0.1 (1 - 0.2)   0.1 * 0.2   0.1 * 0.2

P N H 3 = n R T V = 0 . 1 * 0 . 2 * 0 . 0 8 2 * 3 0 0 2 = 0 . 2 4 6 a t m = P H 2 S

K P = P N H 3 * P H 2 S = ( 0 . 2 4 6 ) 2 = 0 . 0 6 0 5 1 6 = 6 . 0 5 * 1 0 2

x = 6 (Nearest integer).

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