Which of the following sets of quantum numbers are correct?

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Vishal Baghel | Contributor-Level 10

9 months ago

This is a Multiple Choice Questions as classified in NCERT Exemplar

Ans: option (ii) & (iii)

For the given value of n (principal quantum number) the value of l (Azimuthal quantum number) varies from 0 to n-1. However for the given value of l the m_l (magnetic quantum number) varies from -1 to +1.

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Find out the number of following orders which are INCORRECT against the mentioned properties:

(i) Ortho hydrogen > Para hydrogen (Stability at low temperature)

(ii) Ethanol > Glycerol (Viscosity)

(iii) D₂ < He (Boiling point)

(iv) HF > H₂O (Melting point)

(v) H₃BO₃ > BF₃ (Melting point)

(vi) NH₃ < SbH₃ (Boiling point)

(vii) H₂O₂ > H₂O (Strength of hydrogen bond)

(viii) H₂O < D₂O (Freezing point)

(ix) $H F_{2}^{Θ}$ < HF (Strength of hydrogen bond)

(x) D₂O < H₂O (Bond energy)

Vishal Baghel

Kindly go through the answers

(7.00)

Consider the following reaction:
(A substituted phenol reacts with H? and CrO?Cl to produce product 'P'.)
The product ‘P’ gives positive acetyl chloride test. This is because of the presence of which of these –OH group(s)?


Raj Pandey

Kindly consider the following Image

The number of radial land angular nodes in 4d orbital are, respectively

Payal Gupta

In 4d orbital, n = 4 and $l = 2$

Radial nodes = $n - l - 1$

Radial nodes = 4 – 2 – 1 = 1

And angular nodes, $l = 2$

The spin-only magnetic moment value of species is________× 10^-2 BM. (Nearest integer)

[Given:  $\sqrt[]{3} = 1.73]$

Alok Kumar Singh

$B_{2}^{+} \to σ 1 s^{2} s * 1 s^{2} σ 2 s^{2} σ * 2 s^{2} π 2 p^{1}$

Here, number of unpaired electrons, n = 1

Spin only moment ; $μ = \sqrt[]{n (n + 2)} B . M$

= 173 × 10^-2 B.M

Vishal Baghel

$Δ H = Δ U + Δ (P V)$

= $Δ U + P Δ V + V Δ P$

= $Δ U + P Δ V$ (At constant pressure)

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