Which of the following statements are correct? 

(i) Helium has the highest first ionisation enthalpy in the periodic table.

(ii) Chlorine has less negative electron gain enthalpy than fluorine.

(iii) Mercury and bromine are liquids at room temperature.

(iv) In any period, atomic radius of alkali metal is the highest.

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8 months ago

This is a Multiple Choice Questions as classified in NCERT Exemplar

Option (i), (iii)& (iv)

He with 1s2 electronic configuration has the highest electron gain enthalpy in the periodic table. In any period the alkali metals have the lowest effective nuclear charge in that particular period for which it

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Among isoelectronic monoatomic species, size is inversely proportional to atomic number. Hence among isoelectronic species Na? , O²? , N³? , F? (having the nearest noble gas configuration);
Order of size is Na? < F? < O²? < N³?
N³? has least atomic number hence the largest size

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Electron gain enthalpy increases with electro negativity chlorine has higher electron gain enthalpy than fluorine (exception)

In isoelectronic species nuclear charge can be approximated as
Nuclear charge ≈ z / no. of electrons
Al³? Mg²? Na? F? O²? N³?
Nuclear Charge: 13/10 12/10 11/10 9/10 8/10 7/10
Minimum nuclear charge is in N³? and maximum is in Al³?
So order should be
Al³? < Mg²? < Na? < F? < O²? < N³?

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Chemistry NCERT Exemplar Solutions Class 11th Chapter Three 2025

Chemistry NCERT Exemplar Solutions Class 11th Chapter Three 2025

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