Which of the following will produce a buffer solution when mixed in equal volumes?
(i) 0.1 mol dm–3 NH4OH and 0.1 mol dm–3 HCl
(ii) 0.05 mol dm–3 NH4OH and 0.1 mol dm–3 HCl
(iii) 0.1 mol dm–3 NH4OH and 0.05 mol dm–3 HCl
(iv) 0.1 mol dm–3 CH4COONa and 0.1 mol dm–3 NaOH
Which of the following will produce a buffer solution when mixed in equal volumes?
(i) 0.1 mol dm–3 NH4OH and 0.1 mol dm–3 HCl
(ii) 0.05 mol dm–3 NH4OH and 0.1 mol dm–3 HCl
(iii) 0.1 mol dm–3 NH4OH and 0.05 mol dm–3 HCl
(iv) 0.1 mol dm–3 CH4COONa and 0.1 mol dm–3 NaOH
This is a Multiple Choice Questions as classified in NCERT Exemplar
Ans: option (iii)
When 0.1 mol dm-3 NH4OH and 0.05 mol dm-3 HCl react total amount of HCl reacts with NH4OH to form NH4Cl and some NH4OH will be left unreacted. Thus, the resultant solution contains NH4Cl and NH4OH which will produce
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0.01 M NaOH,
M = 1 * 10-2

pOH = 2
pH = 2
Kp = Kc (RT)Dng
36 * 10–2 = Kc (0.0821 * 300)–1
Kc = 0.36 * 0.0821 * 300 = 8.86 » 9
A(g) ->B(g) + (g)
Initial moles n 0 &nbs
On increasing pressure, equilibrium moves in that direction where number of gaseous moles decreases.
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Chemistry NCERT Exemplar Solutions Class 11th Chapter Seven 2025
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