2.27 Estimate the average mass density of a sodium atom assuming its size to be about 2.5 Å. (Use the known values of Avogadro's number and the atomic mass of sodium). Compare it with the mass density of sodium in its crystalline phase: 970 kg/m³. Are the two densities of the same order of magnitude? If so, why?

According to question, we can write

Total moles of gas = n = n_Oxygen + n_Oxygen = $\frac{16}{2}+\frac{128}{32}=12moles$  

Volume of gas = 12 × 22.4 litre = 268.8 litre = 2.688 × 10⁵ cm³ $\approx 27\times 10^{4}c{m}^3$  

$K=\frac{\left(\frac{Q}{r}\right)\mathrm{\Delta }x}{\mathrm{\Delta }AT}$

$\begin{array}{ll}\Rightarrow & \frac{\left({\mathrm{M}\mathrm{L}}^2{\mathrm{T}}^{-2}\right)\left(\mathrm{L}\right)}{\left({\mathrm{L}}^2\right)\left(\theta \right)\left(\mathrm{T}\right)}\\ \Rightarrow \mathrm{}& {\mathrm{M}}^1{\mathrm{L}}^{1-}{\mathrm{T}}^{-3}{\theta }^{-1}\end{array}$

Viscosity = Pascal . Second

$P^X{A}^Y{T}^Z=\left[M^1{L}^{-1}{T}^{-1}\right]$        

=  ${\left[M^1{L}^{+1}{T}^{-1}\right]}^x\left[L^2\right]y{\left[T^1\right]}^z=M^{-1}{L}^{-1}{T}^{-1}$

= x = 1,     x + 2y = -1,      -x + z = 1

y = -1,              Z = 0

Viscosity = [P¹A^-1T⁰]

1 msD = 1mm

10 vsD = 9msD

1vsD = 0.9 MsD

L.C. = 1MSD – 1VSD = 1 – 0.9 = 0.1 mm

Zero error = 4LC = 0.4 mm

Reading = MSR + VSR + correction

= 4.1 cm + 6 * .01 cm + (-0.04 cm) = (4.1 + 0.06 – 0.04) cm

= 4.12 cm = 412 * 10^-2 cm

$\Delta Q=ms\Delta T\Rightarrow s=\frac{\Delta Q}{m\Delta T}\Rightarrow \left[s\right]=\frac{M{L}^2{T}^{-2}}{MQ}=L^2{T}^{-2}{Q}^{-1}$

$\Delta Q=mL\Rightarrow \left[L\right]=\frac{M{L}^2{T}^{-2}}{M}=L^2{T}^{-2}$