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The VSAT syllabus is the set of subjects, topics and sub-topics on which the exam question paper will be based.

  $A^2=\left[\begin{array}{ccc}\hfill 1\hfill & \hfill 0\hfill & \hfill 0\hfill \\ \hfill 0\hfill & \hfill 2\hfill & \hfill 0\hfill \\ \hfill 3\hfill & \hfill 0\hfill & \hfill -1\hfill \end{array}\right]\left[\begin{array}{ccc}\hfill 1\hfill & \hfill 0\hfill & \hfill 0\hfill \\ \hfill 0\hfill & \hfill 2\hfill & \hfill 0\hfill \\ \hfill 3\hfill & \hfill 0\hfill & \hfill -1\hfill \end{array}\right]=\left[\begin{array}{ccc}\hfill 1\hfill & \hfill 0\hfill & \hfill 0\hfill \\ \hfill 0\hfill & \hfill 2^2\hfill & \hfill 0\hfill \\ \hfill 0\hfill & \hfill 0\hfill & \hfill 1\hfill \end{array}\right]$

$A^3=\left[\begin{array}{ccc}\hfill 1\hfill & \hfill 0\hfill & \hfill 0\hfill \\ \hfill 0\hfill & \hfill 2^2\hfill & \hfill 0\hfill \\ \hfill 0\hfill & \hfill 0\hfill & \hfill 1\hfill \end{array}\right]\left[\begin{array}{ccc}\hfill 1\hfill & \hfill 0\hfill & \hfill 0\hfill \\ \hfill 0\hfill & \hfill 2\hfill & \hfill 0\hfill \\ \hfill 3\hfill & \hfill 0\hfill & \hfill -1\hfill \end{array}\right]=\left[\begin{array}{ccc}\hfill 1\hfill & \hfill 0\hfill & \hfill 0\hfill \\ \hfill 0\hfill & \hfill 2^3\hfill & \hfill 0\hfill \\ \hfill 3\hfill & \hfill 0\hfill & \hfill -1\hfill \end{array}\right]$        

$A^4\left[\begin{array}{ccc}\hfill 1\hfill & \hfill 0\hfill & \hfill 0\hfill \\ \hfill 0\hfill & \hfill 2^3\hfill & \hfill 0\hfill \\ \hfill 3\hfill & \hfill 0\hfill & \hfill -1\hfill \end{array}\right]\left[\begin{array}{ccc}\hfill 1\hfill & \hfill 0\hfill & \hfill 0\hfill \\ \hfill 0\hfill & \hfill 2\hfill & \hfill 0\hfill \\ \hfill 3\hfill & \hfill 0\hfill & \hfill -1\hfill \end{array}\right]=\left[\begin{array}{ccc}\hfill 1\hfill & \hfill 0\hfill & \hfill 0\hfill \\ \hfill 0\hfill & \hfill 2^4\hfill & \hfill 0\hfill \\ \hfill 0\hfill & \hfill 0\hfill & \hfill 1\hfill \end{array}\right]$          

Similarly we get A¹⁹ =   $=\left[\begin{array}{ccc}\hfill 1\hfill & \hfill 0\hfill & \hfill 0\hfill \\ \hfill 0\hfill & \hfill 2^{19}\hfill & \hfill 0\hfill \\ \hfill 3\hfill & \hfill 0\hfill & \hfill -1\hfill \end{array}\right]\&A^{20}=\left[\begin{array}{ccc}\hfill 1\hfill & \hfill 0\hfill & \hfill 0\hfill \\ \hfill 0\hfill & \hfill 2^{20}\hfill & \hfill 0\hfill \\ \hfill 0\hfill & \hfill 0\hfill & \hfill 1\hfill \end{array}\right]$

=   $\left[\begin{array}{ccc}\hfill 1\hfill & \hfill 0\hfill & \hfill 0\hfill \\ \hfill 0\hfill & \hfill 4\hfill & \hfill 0\hfill \\ \hfill 0\hfill & \hfill 0\hfill & \hfill 1\hfill \end{array}\right]$

$\Rightarrow 1+\alpha +\beta =1gives\alpha +\beta =0........\left(i\right)$        

  $2^{20}+\left(2^{19}-2\right)\alpha =4from\left(i\right)$

$\Rightarrow \alpha =\frac{4-2^{20}}{2^{19}-2}=\frac{4\left(1-2^{18}\right)}{-2\left(1-2^{18}\right)}=-2$          

So, b = 2

Hence b - a = 4

Freundlich adsorption Isotherm

$\left(\frac{x}{m}\right)=k{\left(P\right)}^{\frac{1}{n}}$

At moderate pressure ; $\frac{x}{m}$ $\frac{}{}$ varies non-linearly with P.

So, $x=\frac{1}{n}$

$l^{-}+H_2{O}_2+2H^{+}\to l_2+2H_{2}O$

(-1) oxidation (0)

Here, I is reducing agent

${}_{}$ $\therefore H_2{O}_2$  behaves like oxidizing agent

Let the equation of normal is Y – y = - $\frac{1}{m}\left(X-x\right)$  

where m is slope of tangent to the given curve then

$Y-y=-\frac{dx}{dy}\left(X-x\right)$           

It passes through (a, b) so b – y = $\frac{-dx}{dy}\left(a-x\right)$  

->(a – x) dx = (y – b) dy

On integration     $ax-\frac{x^2}{2}=\frac{y^2}{2}-by+c.........\left(i\right)$  

(ii) passes through (3, -3) &  $\left(4,-2\sqrt[]{2}\right)$  then

3a – 3b – c = 9       .(ii)

& 4a -  $2\sqrt[]{2}b$ - c = 12           .(iii)

also given   $a-2\sqrt[]{2}b=3............(iv)$

Solve (ii), (iii) & (iv) b = 0, a = 3

Hence a² + b² + ab = 9

In Ce & Eu (+3) oxidation state is more stable

$\therefore C{e}^{+4}+e^{-}\to C{e}^{+3}\left(Reduction\right)$ so CeO₂ is oxidising agent

$E{u}^{+2}\to E{u}^{+3}+e-\left(oxidation\right)$ so EuSO₄ is reducing agent

(1) $H{e}_2^{-}{\sigma }_{1s}^2{\sigma }_{1s}^{*2}{\sigma }_{2s}^{1}B.O=\frac{3-2}{2}=\frac{1}{2}$ ${}_{}^{}{}_{}^{}{}_{}^{}{}_{}^{}\frac{}{}\frac{}{}$

(2) $H{e}_2^{+}{\sigma }_{1s}^2{\sigma }_{1s}^{*1}B.O=\frac{2-1}{2}=\frac{1}{2}$ ${}_{}^{}{}_{}^{}{}_{}^{}\frac{}{}\frac{}{}$

(3) $B{e}_2{\sigma }_{1s}^2{\sigma }_{1s}^{*2}{\sigma }_{2s}^2{\sigma }_{2s}^{*2}B.O=\frac{4-4}{2}=0$ ${}_{}{}_{}^{}{}_{}^{}{}_{}^{}{}_{}^{}\frac{}{}$

So Be2 does not exits

Given $l_{m,n}={\displaystyle {\int }_0^1{x}^{m-1}{\left(1-x\right)}^{n-1}dx............\left(i\right)}$  

put 1 - x = $t\{\begin{array}{l}x=0,t=1\\ x=1,t=0\end{array}$  

dx = -dt

From (i) $l_{m,n}={\displaystyle {\int }_1^0{\left(1-t\right)}^{m-1}.t^{n-1}\left(-dt\right)}$  

$l_{m,n}={\displaystyle {\int }_0^1{t}^{n-1}{\left(1-t\right)}^{m-1}dt={\displaystyle {\int }_0^1{x}^{n-1}{\left(1-x\right)}^{m-1}dx..........\left(ii\right)}}$                              

(i)   $l_{m,n}={\displaystyle {\int }_{\infty }^0\frac{1}{{\left(1+y\right)}^{m-1}}}{\left(1-\frac{1}{1+y}\right)}^{n-1}\left(\frac{-dy}{{\left(1+y\right)}^2}\right)={\displaystyle {\int }_0^{\infty }\frac{y^{n-1}}{{\left(1+y\right)}^{m+n}}dy}..........\left(iii\right)$

Similarly by (ii) $l_{m,n}={\displaystyle {\int }_0^{\infty }\frac{y^{m-1}}{{\left(y+1\right)}^{m+n}}dy..........\left(iv\right)}$  

Adding (iii) & (iv) $2l_{m,n}={\displaystyle {\int }_0^{\infty }\frac{y^{n-1}+y^{m+1}}{{\left(y+1\right)}^{m+n}}}$  

Putting   $\frac{1}{z}\{\begin{array}{l}y=1,z=1\\ y=\infty ,z=0\end{array}$ $\Rightarrow dy=\frac{-1}{z^2}dz$  

Hence  $l_{m,n}={\displaystyle {\int }_0^1\frac{x^{m-1}+x^{n-1}}{{\left(1+x\right)}^{m+n}}}$ dx = a lm, n

-> a = 1

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Kindly go throuigh the solution

Given   ${\displaystyle \sum _{i=1}^{18}\left(x_i-\alpha \right)=36i.e}{\displaystyle \sum _{i=1}^{18}{x}_i-18\alpha =36..........\left(i\right)}$

&       ${\displaystyle \sum _{i=1}^{18}{\left(x_i-\beta \right)}^2=90i.e{\displaystyle \sum _{i=1}^{18}{x_i}^2}}-2\beta {\displaystyle \sum _{}^{}{x}_i+18{\beta }^2=90.............\left(ii\right)}$      

(i) & (ii)   ${\displaystyle \sum _{i=1}^{18}{x_i}^2}=90-18\beta +36\beta \left(\alpha +2\right).............\left(iii\right)$

Now variance ${\sigma }^2=\frac{\sum {x_i}^2}{n}-{\left(\frac{\sum x_i}{n}\right)}^2$ = 1 given

->(a - b) (a - b + 4) = 0

Since $\alpha \ne \beta so\left|\alpha -\beta \right|=4$  

Angle of Ht – B – Ht > angle of Hb – B - Hb

Bond angle $\propto \mathrm{\%}S-Character\propto \frac{1}{\mathrm{\%}ofP-character}$ $\frac{}{}$

${}_{}$  $\angle H_t$ B Ht is more so % P-Character is less.

Given $f\left(x\right)=2x^5+5x^4+10x^3+10x^2+10x+10$

$f\left(-1\right)=3>0\&f\left(-2\right)=-34<0$           

So at least one root will lie in (-2, -1)

now $f\text{'}\left(x\right)=10x^4+20x^3+30x^2+20x+10$  

$=10\left[x^4+2x^3+3x^2+2x+1\right]$            

$=10x^2{\left(x+\frac{1}{x}+1\right)}^2>0\forall x\in R$           

So, f(x) be purely increasing function so exactly one root of f(x) that will lie in (-2, 1). Hence |a| = 2

Kindly consider the following figure

Kindly consider the following figure

$Given\left|z+5\right|\le 4..........\left(i\right)$

->Represent a circle ${\left(x+5\right)}^2+y^2\le 16$  

$=z\left(1+i\right)+\overline{z}\left(1-i\right)\ge -10..........\left(ii\right)$           

->Represent a line X – y $\ge -5$  

So max |z + 1|² = AQ²

$={\left(-4-2\sqrt[]{2}\right)}^2+8$         

$\begin{array}{l}=32+16\sqrt[]{2}\\ =\alpha +\beta \sqrt[]{2}\end{array}$        

Hence a + b = 48

Kindly consider the following figure

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