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There is no difference between these degrees in terms of value and scope. BE and B.Tech have similar scope and future and same is for ME and M.Tech.
Right after independence of India we had two types of universities, one that offered degrees in many fields like Sciences, Arts, Education and Engineering too, and the second set of universities (were named as institutes) offered only degrees in engineering. Universities those offered other degrees along with engineering named their engineering degree as BE (Bachelor of Engineering) and Institute constituted for only Engineering studies named their degree as B.Tech (Bachelor of Technology).
Now as AICTE approve courses most of the courses are same and identical for BE and B.Tech. The universities those offering BE when started new courses named them to B.Tech too.
No degree, BE or B.Tech and ME or M.Tech is superior than other in terms of theory or experiment. BE and B.Tech or ME and M.Tech are same. Both of them are same and have similar scope and future. If there is some notification for BE, B.Tech's are also eligible to apply and vise versa.
What makes the difference is the kind of college/ university you have done your degree from. These days there are many world class universities like Lovely, Amity, Sharda, Manipal etc that are offering wide platform to their students with international exposure and best of best facilities. Students are being offered scholarships and opportunities for research and innovation.