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Yes, you can pursue Company Secretary CS along with a regular law college. However, it may require proper time management and dedication to balance both courses simultaneously. The Institute of Company Secretaries of India (ICSI) is the professional body that governs the CS course in India. The CS course is divided into three levels: Foundation, Executive, and Professional. To pursue CS along with law, you can enroll for the CS Foundation level course while pursuing LL.B. After completing the Foundation level, you can take the Executive level exams while continuing with your LL.B. Finally, after completing your LL.B. Degree, you can take the Professional level exams of the CS course. However, it's important to note that pursuing two courses simultaneously can be challenging, and you must ensure that you can manage the workload and schedule before making a decision.

There are very low chance to get a seat in NITs until 7th round according to your rank. But this year also there will be spot round then you will definitely get a seat in NIT in some branches. M.Sc. In NIT Surat
Biotech engineering, industrial and production engineering, Textile in NIT Jalandhar
There is no chance to get core branch in any NIT. But you may get chemical branch and any local branch like : Metallurgical and biotech and M.Sc. In NIT Silcher, NIT Meghalaya, NIT Agartala, NIT Durgapur, NIT Patna. Disclaimer : I have written this answer according to last years last rank and cut off. There may be variation for this year. Hope it helps.