What is ortho effect?
39 Views|Posted 8 years ago
Asked by Sreedhar Bommidi
1 Answer

Answered by
8 years ago
Hi Sreedhar,
While all substituents on aryl rings can influence acidity by inductive and mesomeric effects, substituents on the ortho position are special. They can also influence acidity significantly by sterics, forcing the carboxylic acid group to bend out of the plane of the benzene ring. Since
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