Account for the following observations: (i) AlCl3 is a Lewis acid (ii) Though fluorine is more electronegative than chlorine yet BF3 is a weaker Lewis acid than BCl3 (iii) PbO2 is a stronger oxidising agent than SnO2 (iv) The +1 oxidation state of thallium is more stable than its +3 state.

Account for the following observations:

(i) AlCl₃ is a Lewis acid (ii) Though fluorine is more electronegative than chlorine yet BF₃ is a weaker Lewis acid than BCl₃

_{(iii) PbO2 is a stronger oxidising agent than SnO2 (iv) The +1 oxidation state of thallium is more stable than its +3 state.}

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Alok Kumar Singh | Contributor-Level 10

10 months ago

This is a Long Answers Type Questions as classified in NCERT Exemplar

As we move down the group in group 13 the participation of s-electrons in bond formation decreases the primary reason behind this is the inert pair effect. In this the p-electrons take part in bond formation and more energy is requ

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Assertion (A): Silicones are water repelling in nature.

Reason (R): Silicones are organosilicon polymers, which have (-R₂SiO-) as repeating unit.

(A) Both A and R are true and R is the correct explanation of A.

(B) Both A and R are true but R is not the correct explanation of A.

(C) Both A and R are not correct.

(D) A is not correct but R is correct.

Alok Kumar Singh

This is a Assertion and Reason Type Questions as classified in NCERT Exemplar

(B)

Silicones are a class of silicon polymers that contain the repeating unit (-R 2 SiO-). Silicones are water repellent in nature because they are surrounded by non-polar alkyl groups, so A and R are both correct, but R is

Alok Kumar Singh

This is a Assertion and Reason Type Questions as classified in NCERT Exemplar

(A)

In aluminium silicate, silicon is doped with group 13 elements and as aluminium is trivalent and silicon is tetravalent so, on replacing aluminium by Silicon, a negatively charged structure will be obtained. Both the st

Alok Kumar Singh

This is a Matching Type Questions as classified in NCERT Exemplar

(i)→ (b), (ii) → (c), (iii) → (b), (iv) → (a) (v)→ (b) (vi)→ (c)

Match the species given in Column I with properties given in Column II.

Column I

Column II

(i) Diborane

(a) Used as a flux for soldering metals

(ii) Gallium

(b) Crystalline form of silica

(iii) Borax

(c) Banana bonds

(iv) Aluminosilicate

(d) Low melting, high boiling, useful for measuring high temperatures

(v) Quartz

(e) Used as catalyst in petrochemical industries.

Alok Kumar Singh

This is a Matching Type Questions as classified in NCERT Exemplar

(i)→ (c) (ii)→ (d) (iii)→ (a) (iv)→ (e) (v)→ (b)

Match the species given in Column I with the properties mentioned in Column II.

Column I

Column II

(i) BF₄⁻

(a) Oxidation state of central atom is +4

(ii) AlCl₃

(b) Strong oxidising agent

(iii) SnO

(c) Lewis acid

(iv) PbO₂

(d) Can be further oxidised

(e) Tetrahedral shape

Alok Kumar Singh

This is a Matching Type Questions as classified in NCERT Exemplar

(i)- (e), (ii)- (c), (iii)- (d), (iv)- (a) & (b)

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Chemistry NCERT Exemplar Solutions Class 11th Chapter Eleven 2025

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(i) Boron in [B(OH)₄]⁻	(a) sp²
(ii) Aluminium in [Al(H₂O)₆]³⁺	(b) sp³
(iii) Boron in B₂H₆	(c) sp³d²
(iv) Carbon in Buckminsterfullerene
(v) Silicon in SiO₄⁴⁻
(vi) Germanium in [GeCl₆]²⁻

Column I	Column II
(i) Diborane	(a) Used as a flux for soldering metals
(ii) Gallium	(b) Crystalline form of silica
(iii) Borax	(c) Banana bonds
(iv) Aluminosilicate	(d) Low melting, high boiling, useful for measuring high temperatures
(v) Quartz	(e) Used as catalyst in petrochemical industries.

Column I	Column II
(i) BF₄⁻	(a) Oxidation state of central atom is +4
(ii) AlCl₃	(b) Strong oxidising agent
(iii) SnO	(c) Lewis acid
(iv) PbO₂	(d) Can be further oxidised
	(e) Tetrahedral shape