Catenation, i.e. linking of similar atoms depends on size and electronic configuration of atoms. The tendency of catenation in Group 14 elements follows the order
(A) C>Si>Ge>Sn
(B) C>>Si>Ge≈Sn
(C) Si>C>Sn>Ge
(D) Ge>Sn>Si>C
Catenation, i.e. linking of similar atoms depends on size and electronic configuration of atoms. The tendency of catenation in Group 14 elements follows the order
(A) C>Si>Ge>Sn
(B) C>>Si>Ge≈Sn
(C) Si>C>Sn>Ge
(D) Ge>Sn>Si>C
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1 Answer
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This is a Multiple Choice Questions as classified in NCERT Exemplar
B
In group 14, as we move down from C to Sn, the size increases and electronegativity decreases. This results in the decrease in M-M bond energy. Hence the catenation property decreases.
Bond energy is the amount of energy required to fragment the atoms combined in a molecule are born into separate atoms. Carbon has maximum bond energy as compared to its other group elements. Therefore, shows maximum catenation property.
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