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Hi although UPSC does not mention horticulture as a subject of eligibility you are eligible if your B.Sc. horticulture contains any of the following subject
Animal Husbandry & Veterinary Science, Botany, Chemistry, Geology, Mathematics, Physics, Statistics and Zoology, agriculture and forestry
Horticulture is a subject inseparabale from Agriculture hence treated as an agriculture subject only hence you are eligible.
The eligibility is as follows:
Age-limits
21-30 Years on 1st July of the year of examination
A Bachelor's degree with at least one of the subjects namely, Animal Husbandry & Veterinary Science, Botany, Chemistry, Geology, Mathematics, Physics, Statistics and Zoology or a Bachelor's degree in Agriculture or Forestry or Engineering of a recognised university or equivalent.
Candidates appearing at their degree examination (with prescribed subjects) are also eligible to compete. Candidates qualifying on the result of the written part of the examination will be required to submit the proof of passing the requisite examination alongwith their detailed application form to be filled up at that stage.
so go ahead and apply

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