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Hi Karan,
Firstly, It depends upon the cutoff marks for your shortlisting in these branches. To get an idea, please go through this link:
http://www.bitsadmission.com/cutoffscores2017.aspx
For the understanding of the difference, between the two branches, both have origin in Electrical Engineering. But in detail, Electronics and Instrumentation Engineering deals with Electrical technology and machines, circuit analysis, electronics, electromagnetism, electrical engineering materials, instrumentation etc while ECE consist of analog transmission, basic electronics, solid state devices, microprocessors, digital and analog communication, analog integrated circuits, manufacturing of electronic devices, circuits etc. BITS Goa and Hyderabad are both at par with each other with the aspect of these branches.
Best wishes.

Hi Sumeet, D.Ed. Course is technically an elementary teacher training course. Diploma in Education is similar to D. El. Ed. (Diploma in Elementary Education), JBT, D. T. Ed. (Diploma in Teachers Education) and ETT (Elementary Teacher Training) courses. D.Ed. , JBT, D. El. Ed. , D. T. Ed. And ETT courses have similar syllabus and course structure. These courses also offer similar job opportunities. After completing Diploma in Education course, successful candidates may work as elementary level teachers at educational institutes. They may find work at institutes imparting elementary level education, like
Government schools
Private schools
Nursery
Coaching/Private tuition classes
Day care centres
D. El. Ed. Is a job oriented teacher training course. If you are interested in teaching at elementary level, this course is for you! You may join the course right after completing 12th. If you are interested in teaching at a higher level, you may check out this list of teacher training courses. Here are some other teacher training courses for you- D.Ed. & JBT. I hope you make a right choice. All the best.