Account for the following observations:

(i) AlCl3 is a Lewis acid                                    (ii) Though fluorine is more electronegative than chlorine yet BF3 is a weaker Lewis acid than BCl3      

(iii) PbO2 is a stronger oxidising agent than SnO2       (iv) The +1 oxidation state of thallium is more stable than its +3 state.

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    alok kumar singh | Contributor-Level 10

    5 months ago

    This is a Long Answers Type Questions as classified in NCERT Exemplar

    As we move down the group in group 13 the participation of s-electrons in bond formation decreases the primary reason behind this is the inert pair effect. In this the p-electrons take part in bond formation and more energy is required to unpair the valence electrons to make them participate in bonding. Due to this the lower oxidation state of elements becomes stable than the higher oxidation state. As for thallium, +1 oxidation state is more stable than +3.

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