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Hi,
Well, I would say that both are very different.
1. CA is a professional degree which if accompanied with graduation and Masters offers value added services. Whereas I.A.S is civil services, and to sit for the same, graduation in any discipline is must.
2. CA offers jobs in both public and private sector while civil services are only offered at government level.
3. Canada, New Zealand, Australia are three top recruiters of accountants (you need to sit for a few exams) while there is no option of getting posted abroad as an I.A.S officer.
So, you may take up a graduation of 3 years in relevant field of commerce, go for CA also side by side and then further you may take up civil service (age limit is 21-30 years). Make sure once you are done with the article ship, then you go for writing the exam.
There are companies in India hiring large number of CA professionals. To name a few, I can suggest you with Ernst & Young, HSBC Bank, ICICI Prudential, Om Kotak Mahindra, Birla Sun-Life, Tata AIF Life, Reliance, HDFC Standard Life, Max New York Life, Banks like SBI, HSBC, Bureau of Public Enterprises, government financial institutions and stock exchanges, universities, etc
While IAS joins the state administration at the divisional level, as a sub-magistrate, and looks after law and order, general administration and development work in the area under his charge.
Feel free to revert. In case it resolves, appreciate by liking it or marking as best.
All the best.

Hello Sonu,
Benefits:
Insurance: All Air Force personnel, including Flight Cadets are provided life insurance cover under the Air Force Group Insurance Scheme ( AFGIS). Monthly contribution rates are minimal and the insurance policy covers all contingencies. As an Air Force Officer you are insured for an amount of Rs 50 Lacs with an additional insurance cover of Rs 10 Lacs for pilots and Loans :As a member of AFGIS, you can avail following loans:House Building Loan
Computer Loan
Conveyance Loan
Medical : All Air Force officers, their families and dependents have free access to medical rooms and hospitals equipped with the best of facilities. Apart from being treated at the Armed Forces Hospitals, there are also tie-ups with Civil Hospitals for treatment of specialised cases, if required. Patients are also given grants for purchase of necessary medical equipment and mechanical aid to help make them self reliant. Scholarships and welfare schemes from AFWWA ( Air Force wives welfare association)and Accommodation: Free accommodation for serving personnel of Indian air force, Annual leave for 60 days and casual leave of 20 days per year and Ration facility in Indian air force and institute and messes membership.
Various institute and mess memberships for serving personnel and Rail concessions: Get free and concession in rail tickets and secured camp life.
Secured air force campus with state of the art security, CSD facilities
Canteen store department facilities. Sports facilities: Various sports inside air force campus like, basketball, football, cricket, gym etc. And Educational Opportunities Once you join the Air Force, you realise that behind all the action and adventure is a lot of effort towards academic pursuits. From the moment you are selected, until the time you retire, you are continuously honing your skills with a large number of in-service courses and other educational avenues. If you join the Air Force through NDA, you earn yourself a Bachelors Degree in Science or Computer Science. The IAF also sponsors M.Tech. Courses for officers of the Technical Branch, in institutes like IIT and BHU-IT. The IAF also has tie-ups with universities like IGNOU to facilitate long-distance learning for officers and airmen.
Leave: They are also allowed study leave of up to 24 months extendable up to 28 months.
Good luck.