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Hi Pramila,
MSW(medical & Psychiatry) can get you government jobs in the areas like NGOs approved by the different state governments, Public health Offices which are mostly run by the govt. bodies. Also one can look for the jobs in various trauma centers/ colleges in teaching department etc.
As for the CC Certificate is concerned, definitely the same offers a lot of add on value but I doubt if this allows you to gain any concession.
Coming to the last part of your query, There are several NGOs (Private / Govt regd) and following are the few:
All India Womens Conference
Aruna Asaf Ali Memorial Trust
Rotary Club
Indian Council Of Social Welfare
Nari Jagriti Manch and many more.
Kindly revert for any further queries, also if you liked this answer then rate it 'Best answer' or give a 'Thumbs Up' rating.
All the best!

Hi Saranya, to pursue BE abroad, you need to prepare you application. Gaining admission will greatly depend on what grades you have scored in DCE. Documents required - Class 10 and 12 marksheets and Passing certficate, sem wise or year wise marksheets, degree certificate or provsional certificate, Statement of Purpose, Letter of Recommendation(2), Work experience letters from all employers (if any), CV (if you have work ex), A copy of your passport(1st and Last Page), IELTS ( 6 min for UG courses). IELTS can be submitted later on if not already written. With all these documents and a filled up application form you need to apply to the University for admission.
If you like this answer then kindly mark it as the best answer or rate it thumbs up. Please feel free to post queries if you have any.